| 1. Identity statement | ||||
| Reference Type | Journal Article | |||
| Site | mtc-m21d.sid.inpe.br | |||
| Holder Code | isadg {BR SPINPE} ibi 8JMKD3MGPCW/3DT298S | |||
| Identifier | 8JMKD3MGP3W34T/4A3AL7S | |||
| Repository | sid.inpe.br/mtc-m21d/2023/10.17.19.07 (restricted access) | |||
| Last Update | 2023:10.17.19.07.19 (UTC) simone | |||
| Metadata Repository | sid.inpe.br/mtc-m21d/2023/10.17.19.07.19 | |||
| Metadata Last Update | 2024:01.02.17.16.49 (UTC) administrator | |||
| DOI | 10.1016/j.electacta.2023.143130 | |||
| ISSN | 0013-4686 | |||
| Citation Key | VernasquiFerrSaezRodr:2023:EnElPr | |||
| Title | Enhancing electrochemical production of peroxophosphates using new boron doped diamond coatings  | |||
| Year | 2023 | |||
| Month | Sept. | |||
| Access Date | 2024, May 19 | |||
| Type of Work | journal article | |||
| Secondary Type | PRE PI | |||
| Number of Files | 1 | |||
| Size | 2145 KiB | |||
| 2. Context | ||||
| Author | 1 Vernasqui, Laís Gimenes 2 Ferreira, Neidenêi Gomes 3 Saez, C. 4 Rodrigo, Manuel A. | |||
| Resume Identifier | 1 2 8JMKD3MGP5W/3C9JHU3 | |||
| Group | 1 CMS-ETES-DIPGR-INPE-MCTI-GOV-BR 2 COPDT-CGIP-INPE-MCTI-GOV-BR | |||
| Affiliation | 1 Instituto Nacional de Pesquisas Espaciais (INPE) 2 Instituto Nacional de Pesquisas Espaciais (INPE) 3 TEQUIMA Research Group 4 TEQUIMA Research Group | |||
| Author e-Mail Address | 1 lais.vernasqui@inpe.br 2 3 4 manuel.rodrigo@uclm.es | |||
| Journal | Electrochimica Acta | |||
| Volume | 467 | |||
| Pages | e143130 | |||
| Secondary Mark | A1_SAÚDE_COLETIVA A1_INTERDISCIPLINAR A1_FARMÁCIA A1_ENGENHARIAS_II A2_QUÍMICA A2_MEDICINA_II A2_MEDICINA_I A2_MATERIAIS A2_ENGENHARIAS_III A2_CIÊNCIAS_BIOLÓGICAS_II A2_CIÊNCIAS_BIOLÓGICAS_I A2_CIÊNCIAS_AMBIENTAIS A2_BIOTECNOLOGIA B1_ASTRONOMIA_/_FÍSICA | |||
| History (UTC) | 2023-10-17 19:07:19 :: simone -> administrator :: 2023-10-17 19:07:20 :: administrator -> simone :: 2023 2023-10-17 19:07:40 :: simone -> administrator :: 2023 2024-01-02 17:16:49 :: administrator -> simone :: 2023 | |||
| 3. Content and structure | ||||
| Is the master or a copy? | is the master | |||
| Content Stage | completed | |||
| Transferable | 1 | |||
| Content Type | External Contribution | |||
| Version Type | publisher | |||
| Keywords | Peroxophosphate Monoperoxophosphoric acid Diamond electrodes Electrolysis Ultrananocrystalline Microcrystalline | |||
| Abstract | Two boron doped ultrananocristallyne diamond (UNC) electrodes were manufactured and compared with a standard microcrystalline commercial electrode, to clarify how their differences may affect to the production of oxidants in the electrolysis of solutions containing phosphoric acid or phosphate salts. Effects of the current density and electrolyte pH were evaluated. Significant differences were found in the production of oxidants, being the production of oxidants favored, at high current densities and alkaline pHs. The effect of the pH was explained in terms of the higher stability of the peroxodiphosphate anion in comparison with the monoperox-yphosphate acid produced at low pHs. As well, because of the improved electrostatic attraction of the anion with the anode. Despite not exhibiting the largest electrochemical surface area, the flat UNC electrode shows the best performance for this process, except for the operation at low current densities and alkaline pHs in which the porous UNC outperforms it. Better efficiencies are obtained operating at mild current densities which was explained in terms of the great significance of direct processes in the production of oxidants by electrolysis of phosphoric acid or phosphate solutions. | |||
| Area | FISMAT | |||
| Arrangement 1 | urlib.net > BDMCI > Fonds > Produção pgr ATUAIS > CMS > Enhancing electrochemical production... | |||
| Arrangement 2 | urlib.net > BDMCI > Fonds > Produção a partir de 2021 > CGCE > Enhancing electrochemical production... | |||
| Arrangement 3 | urlib.net > BDMCI > Fonds > Produção a partir de 2021 > CGIP > Enhancing electrochemical production... | |||
| doc Directory Content | access | |||
| source Directory Content | there are no files | |||
| agreement Directory Content |
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| 4. Conditions of access and use | ||||
| Language | en | |||
| Target File | 1-s2.0-S0013468623013026-main.pdf | |||
| User Group | simone | |||
| Reader Group | administrator simone | |||
| Visibility | shown | |||
| Archiving Policy | denypublisher denyfinaldraft24 | |||
| Read Permission | deny from all and allow from 150.163 | |||
| Update Permission | not transferred | |||
| 5. Allied materials | ||||
| Next Higher Units | 8JMKD3MGPCW/3F358GL 8JMKD3MGPCW/46KTFK8 8JMKD3MGPCW/46KUES5 | |||
| Citing Item List | sid.inpe.br/bibdigital/2013/10.14.21.39 1 sid.inpe.br/mtc-m21/2012/07.13.14.56.52 1 sid.inpe.br/bibdigital/2022/04.03.17.52 1 | |||
| Dissemination | WEBSCI | |||
| Host Collection | urlib.net/www/2021/06.04.03.40 | |||
| 6. Notes | ||||
| Empty Fields | alternatejournal archivist callnumber copyholder copyright creatorhistory descriptionlevel e-mailaddress format isbn label lineage mark mirrorrepository nextedition notes number orcid parameterlist parentrepositories previousedition previouslowerunit progress project rightsholder schedulinginformation secondarydate secondarykey session shorttitle sponsor subject tertiarymark tertiarytype url | |||
| 7. Description control | ||||
| e-Mail (login) | simone | |||
| update | ||||